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  • Lezione 6 (Organic Chemistry - Paolo Tecilla)
    • Structure of Conjugated Dienes
    • Stability of Conjugated Dienes
    • π Molecular Orbitals of 1,3-Butadiene
    • π Molecular Orbitals of the Allyl Cation and Anion
    • π Molecular Orbitals of the Allyl Radical
    • Electrophilic 1,2- and 1,4-Addition of HX to 1,3-Butadiene
    • Electrophilic 1,2- and 1,4-Addition of X₂ to 1,3-Butadiene
    • Electrophilic Addition of HX to 1,3-Butadiene: Thermodynamic vs Kinetic Control
    • UV–Vis Spectroscopy of Conjugated Systems
    • UV–Vis Spectroscopy: Woodward–Fieser Rules
    • Pericyclic Reactions: Introduction
    • Thermal and Photochemical Electrocyclic Reactions: Overview
    • Thermal Electrocyclic Reactions: Stereochemistry
    • Photochemical Electrocyclic Reactions: Stereochemistry
    • Cycloaddition Reactions: Overview
    • Cycloaddition Reactions: MO Requirements for Thermal Activation
    • Cycloaddition Reactions: MO Requirements for Photochemical Activation
    • [4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction
    • Diels–Alder vs Retro-Diels–Alder Reaction: Thermodynamic Factors
    • Diels–Alder Reaction Forming Cyclic Products: Stereochemistry
    • Diels–Alder Reaction: Characteristics of Dienes
    • Diels–Alder Reaction: Characteristics of Dienophiles
    • Thermal Sigmatropic Reactions: Overview
    • [3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement
    • [3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement
    • Woodward–Hoffmann Selection Rules and Microscopic Reversibility

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